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发表于 2026-6-12 15:16:18
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Direct deaminative functionalization with N-nitroamines
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G. Tu, K. Xiao, X. Chen, H. Xu, H. Zeng, F. Zhang, X.-S. Xue*, X. Zhang* Nature 2025, 648, 341-348.$ N6 G+ x ^) q8 T
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$ c/ ?6 L3 s) n* P/ j6. C(sp3)-F Bond Activation by Lewis Base-Boryl Radicals via Concerted Electron-Fluoride Transfer
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X. Guo, Y. Zhang, X. Lai, Y. Pang, X.-S. Xue* Angew. Chem. Int. Ed. 2025, e202415715.
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1 V9 Q3 ^$ f6 k" F, k9 N7. Computational analysis of modular diazotransfer reactions for the development of predictive-reactivity models and diazotransfer reagents/ G6 a6 c! }8 f) R- w" H1 V" x
E! [2 D% Q. C! f6 j3 b4 hM.-M. Zheng, L. Cai, T. Ma, H.-D. Tan, X. Lai, J. Dong*, X.-S. Xue* Nat. Synth. 2024, 3, 1507-1517.
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& n4 D3 g) ?- [# X; P7 Y8. Catalyst-Substrate Helical Character Matching Determines the Enantioselectivity in the Ishihara-Type Iodoarenes Catalyzed Asymmetric Kita-Dearomative Spirolactonization! P! s8 L2 h' j3 `. O
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H. Zheng, C. Liu, M. Pan, M. Uyanik, K. Ishihara, X.-S. Xue* J. Am. Chem. Soc. 2023, 145, 7301-7312.
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9. Oxidative addition of an alkyl halide to form a stable Cu(III) product5 Q5 q$ E+ E/ A3 ~. S$ p+ b- k
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Y. Luo, Y. Li, J. Wu, X.-S. Xue*, J. F. Hartwig*, Q. Shen* Science 2023, 381, 1072-1079. |
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